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Characteristics of current roadside pollution under different environmental conditions fundamentals for the development of a new roadside pollution monitoring concept

Fachliche Zuordnung Physik des Erdkörpers
Förderung Förderung von 2010 bis 2016
Projektkennung Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 166043401
 
Erstellungsjahr 2015

Zusammenfassung der Projektergebnisse

In a bilateral German-Polish collaboration and involving scientists from China, India, Nepal, Finland, Greece and Tajikistan, we studied typical traffic pollutants at roadsides, and investigated the possible use of magnetic parameters as fast and convenient proxy. For monitoring, we removed 10-15 cm of top soil near the roadside and replaced it by plastic boxes with clean quartz sand. At two sites, we additionally installed samplers in different heights (ground, 0.5 m, 2 m). Related to the aims of the study, we achieved the followings main results: (1) Within 24 months of exposure, magnetic susceptibility (MS) and heavy metal (HM) contents increased, but with highly diverse differences between sites. Significant correlation of MS with HMs and also with polycyclic aromatic hydrocarbons (PAHs) was observed. (2) The origin of traffic pollutants was confirmed by increased contents of typical anthropogenic HMs (Pb, Zn, Cd, Cu) and a good correlation between Ti and Mo contents, which do not occur in natural associations. Ratios between particular PAHs and high contents of typical PAHs from vehicle emissions also imply traffic as the main source. (3) Systematic differences of MS, PAHs and HMs concentrations in samplers at different heights and distances from the road indicate a common pathway of magnetic particles and pollutants, and a dominant transport by splash-water. (4) Magnetite is the main magnetic mineral collected in the samplers. High correlation between MS and the total Fe content indicates that Fe mainly occurs as ferrimagnetic phases originating from traffic emissions. (5) The results show that under defined conditions, MS can be used as an indicator of soil pollution caused by traffic emissions. An appropriate roadside monitoring protocol based on magnetic signatures should best use a single thin (1-2 cm) layer of clean quartz sand protected against lateral translocation of soil. Long-term maintenance of monitoring plots turned out to be a logistic challenge due to vandalism, traffic influences, and weather conditions.

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