Einkristalldiffraktometer

• Subject Area: Chemical Solid State and Surface Research
• Term: Funded in 2007
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 55232290

• Final Report Year: 2012

Final Report Abstract

Synthese und Charakterisierung von labilen Pniktogen-Stickstoffverbindungen des Typs: (i) fünf-gliedrige Heterocyclen (ii) cyclo-Dipnikta-diazane und deren Kationen (iii) E2N2 Biradikaloide (iv) PN-Oligomere Synthese und Charakterisierung von ionischen Flüssigkeiten. Synthese und Charakterisierung von CN-basierten Anionen und Adduktanionen sowie deren Einsatz zu Synthese von Koordinationspolymeren. Synthese und Charakterisierung von binären CN-Verbindungen. Synthese und Charakterisierung von Salzen mit Silyliumkationen und deren Einsatz in der Synthesechemie unter Verwendung von super Lewis-sauren Medien.

Publications

• Staudinger Reaction as a Way Out To Avoid Cyclization in the Reaction of Silylated Dichloro(hydrazino)phosphane with Trimethylsilyl Azide. European Journal of Inorganic Chemistry, Vol. 2008, Issue 27, pp. 4199–4203.
  A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1002/ejic.200800446)
• Tetrazarsole – eine neue Klasse binärer Arsen-Stickstoff-Heterocyclen / Tetrazarsoles — A New Class of Binary Arsenic–Nitrogen Heterocycles. Angewandte Chemie, Vol. 120. 2008, Issue 3, pp. 614–617; Angewandte Chemie International Edition, Vol. 47. 2008, Issue 3, pp. 603–606. http://dx.doi.org/10.1002/anie.200704367
  A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1002/ange.200704367)
• Titanocene-mediated formation of phosphorus-phosphorus bonds. Organometallics, Vol. 27. 2008, Issue 7, pp 1393–1398.
  M. Schaffrath, A. Villinger, D. Michalik, U. Rosenthal, A. Schulz
  (See online at https://dx.doi.org/10.1021/om701038p)
• Hypersilylated Cyclodiphosphadiazanes and Cyclodiphosphadiazenium Salts. Dalton Transactions, Issue 42. 2009, pp. 9304 – 9311.
  R. Kutzora, A. Schulz, A. Villinger, R. Wustrack
  (See online at https://dx.doi.org/10.1039/B911326F)
• Salts and Ionic Liquids of Resonance Stabilized Amides. Chemistry – An Asian Journal, Vol. 4. 2009, Issue 10, pp. 1588–1603.
  A. Schulz, H. Brand, A. Villinger
  (See online at https://dx.doi.org/10.1002/asia.200900181)
• Synthesis, Structure, and Bonding of Weakly Coordinating Anions Based on CN-Adducts. J. Am. Chem. Soc. 2009, 131, 8958 – 8970. Journal of the American Chemical Society, Vol. 131. 2009, Issue 25, pp 8958–8970
  A. Bernsdorf, H. Brand, R. Hellmann, M. Köckerling, A. Schulz, A. Villinger, K. Voss
  (See online at https://dx.doi.org/10.1021/ja902450b)
• Preparation and Characterization of [CF3SO3(SiMe3)2]+[B(C6F5)4]–. Chemical Communications, Vol. 46. 2010, Issue 21, pp. 3696 – 3698.
  A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1039/C0CC00013B)
• Pseudohalonium Ions: [Me3Si–X–SiMe3]+ (X=CN, OCN, SCN, and NNN). Chemistry - A European Journal, Vol. 16. 2010, Issue 24, pp. 7276–7281.
  A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1002/chem.201000289)
• Synthesis and Characterization of 1,3-Dihalogeno-2,4-bis(2,4,6-tri-tert-butylphenyl)-cyclo-1,3-distiba-2,4-diazanes, [X–Sb(m-NR)]2 (X = F, Cl, Br, and I). European Journal of Inorganic Chemistry, Vol. 2010, Issue 35, pp. 5501–5508.
  M. Lehmann, A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1002/ejic.201000885)
• Synthesis of Sterically Encumbered 2,4-Bis-m-Terphenyl-1,3-Dichloro-2,4- cyclo-Dipnictadiazanes [m-TerNPnCl]2, (Pn = P, As). Dalton Transactions, Issue 39. 2010, pp. 9962 – 9972.
  F. Reiß, A. Schulz, A. Villinger, N. Weding
  (See online at https://dx.doi.org/10.1039/C0DT00700E)
• A Lewis Acid Assisted Methyl/Chlorine Exchange In Silylated Hydrazinochlorophosphanes. Inorganic Chemistry, Vol. 50. 2011, Issue 6, pp. 2691–2702.
  A. Westenkirchner, A. Villinger, K. Karaghiosoff, R. Wustrack, D. Michalik, A. Schulz
  (See online at https://dx.doi.org/10.1021/ic200005q)
• Eine ungewöhnliche Isomerisierung zu Tetraazastibolen† / An Unusual Isomerization to Tetrazastibol. Angewandte Chemie, Vol. 123. 2011, Issue 22, pp. 5327–5331; Angewandte Chemie International Edition, Vol. 50. 2011, Issue 22, pp. 5221–5224. http://dx.doi.org/10.1002/anie.201100663
  M. Lehmann, A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1002/ange.201100663)
• Ionic Liquids Containing the Triply Negatively Charged Tricyanomelaminate Anion and a B(C6F5)3 Adduct Anion. Chemistry - A European Journal, Vol. 17. 2011, Issue 48, pp. 13526–13537.
  K. Voss, M. Becker, A. Villinger, V. N. Emel’yanenko, R. Hellmann, B. Kirchner, F. Uhlig, S. P. Verevkin, A. Schulz
  (See online at https://dx.doi.org/10.1002/chem.201101946)
• Mono- and Diazides of Bismuth. Organometallics, Vol. 30. 2011, pp. 284 – 289.
  A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1021/om1009796)
• P(m-NTer)]2: A High Temperature Stable Biradicaloid. Angewandte Chememie, Vol. 123. 2011, pp.9136 – 9130; Angewandte Chemie International Edition, Vol. 50. 2011, Issue 38, pp. 8974–8978.
  T. Beweries, R. Kuzora, U. Rosenthal, A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1002/anie.201103742)
• Silylium-Arene Adducts: An Experimental And Theoretical Study. Journal of the American Chemistry Society, Vol.133. 2011, issue 51, pp. 21016–21027.
  M. Farooq Ibad, P. Langer, A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1021/ja209693a)
• Sulfate and Nitrate Adduct Anions. RSC Advances, Issue 1. 2011, pp. 128 – 134.
  M. Becker, A. Schulz, A. Villinger, K. Voss
  (See online at https://dx.doi.org/10.1039/C1RA00186H)
• Synthesis of Blue Imino(pentafluorophenyl)phosphane. Inorganic Chemistry, Vol. 50, 2011, Issue 12, pp. 5784–5792.
  M. Kuprat, M. Lehmann, A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1021/ic200623x)
• Binary Pnictogen Azides - An Experimental and Theoretical Study: [As(N3)4]-, [Sb(N3)4]- and [Bi(N3)5(DMSO)]2-. Chemistry - A European Journal, Vol. 18.2012, Issue 10, pp. 2902–2911.
  A. Schulz, A. Villinger
  (See online at https://dx.doi.org/10.1002/chem.201102656)
• The N,N-Bis-terphenyl-amino-phosphenium Cation - A Sensitive Probe For The Interactions With Different Anions. European Journal of Inorganic Chemistry, Vol. 2012, Issue 2, pp. 261–271.
  F. Reis, A. Villinger, A. Schulz
  (See online at https://dx.doi.org/10.1002/ejic.201100978)