Fast in situ - spectroscopy of electrocatalytic fuel cell reactions - Methodic development and mechanistic studies

Applicant Professor Dr. Rolf Jürgen Behm
Subject Area Physical Chemistry of Solids and Surfaces, Material Characterisation
Term from 2004 to 2009
Project identifier Deutsche Forschungsgemeinschaft (DFG) - Project number 5417575
 

Final Report

Final Report Year 2008

No abstract available

Publications

  • Bridge-bonded formate - Active intermediate or spectator Species in formic acid oxidation on a Pt film electrode?, Langmuir, 22 (25), 10399, 2006
    Y.-X. Chen, M. Heinen, Z. Jusys and R.J. Behm
  • Adsorption and oxidation of ethanol on colloid-based Pt/C, PtRu/C and Pt3Sn/C catalysts: In-situ FTIR spectroscopy and on-line DEMS studies. Chem. Phys. Phys. Chem. 9 (2007) 2686-2696
    Q. Wang, G.Q. Sun, L.H. Jiang, Q. Xin, S.G. Sun, Y.X. Jiang, S.P. Chen, Z. Jusys, and R.J. Behm
  • CO adsorption kinetics and adlayer build-up studied by combined ATR-FTIR spectroscopy and on-line DEMS under continuous flow conditions, Electrochim. Acta, 53, 1279, 2007
    M. Heinen, Y.-X. Chen, Z. Jusys, and R.J. Behm
  • In situ ATR-FTIRS coupled with on-line DEMS under controlled mass transport conditions - A novel tool for electrocatalytic reaction studies, Electrochim. Acta, 52, 5634, 2007
    M. Heinen, Y.-X. Chen, Z. Jusys, and R.J. Behm
  • Kinetic isotope effects in complex reaction networks - An in-situ IR study on formic acid electrooxidation on Pt under controlled mass transport conditions, Chem. Phys. Chem., 8, 380, 2007
    Y.-X. Chen, M. Heinen, Z. Jusys, and R.J. Behm
  • Potential-Induced COad Island Formation on a Platinum Thin-Film Electrode in the H-upd Potential Region, J. Phys. Chem. C, 111, 435, 2007
    Y.-X. Chen, M. Heinen, Z. Jusys, and R.J. Behm
  • Room temperature COad desorption/exchange on Pt electrodes -A combined in-situ IR and mass spectrometry study, Chem. Phys. Chem., 8, 2484, 2007
    M. Heinen, Y.-X. Chen, Z. Jusys, and R.J. Behm
  • Electrooxidation of small organic C2 molecules studied by IRS and combined IRS/DEMS measurements, Ph.D. Thesis, Ulm University (2008)
    Martin Heinen
DFG Programme Research Grants