Bifunktionelle Katalysatoren auf Rotaxanbasis als Modelle für Multienzymkomplexe, Studien zu molekularen Motoren

• Applicant: Professor Dr. Christoph A. Schalley
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2000 to 2008
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 5242796

• Final Report Year: 2009

Final Report Abstract

No abstract available

Publications

• Controlling the rate of shuttling motions in [2]rotaxanes by electrostatic interactions: a cation as solvent-tunable brake. Org. Biomol. Chem. 2005, 2691-2700
  P. Ghosh, G. Federwisch, M. Kogej, C. A. Schalley, D. Haase, W. Saak, A. Lützen, R. Gschwind
  
• A synthetic approach lowards interlocked pi-conjugated macrocycles. Eur. J. Org. Chem. 2006, 8, 1940-1948
  M. Amman, P. Bäuerle, A. Rang, C. A. Schalley
  
• Highly ordered two-dimensional hydrogen bonded structures of a large tetralactam macrocycle on the Au(111) surface. Adv. Funct. Mater. 2007, 17, 513-519
  I. Kossev, W. Reckien, B. Kirchner, T. Felder, M. Nieger, C. A. Schalley, F. Vögtle, M. Sokolowski
  
• Synthesis and electronic properties of the first "pi-conjugated catenane" - A novel topological structure in the field of conjugated oligomers and polymers. Angew. Chem. 2007, 119, 367-372; Angew. Chem. Int. Ed 2007, 46, 363-368
  M. Ammann, M. Wilde, G. Götz, E. Mena-Osteritz, A. Rang, C. A. Schalley, P. Bäuerle
  
• A Modular "Toolbox" Approach to Flexible Branched Multi-Macrocyclic Hosts as Precursors for Multiply Interlocked Architectures. Chem. Eur. J. 2008, 14, 10012-10028
  B. Baytekin, S. S. Zhu, B. Brusilowskij, J. Illigen, J. Ranta, J. Huuskonen, K. Rissanen, L. Kaufmann, C. A. Schalley
  
• How can rotaxanes be modified by varying functional groups at the axle? A combined theoretical and experimental analysis of thermochemistry and electronic effects. Chem. Eur. J. 2008, 14, 1216- 1227.
  C. Spickermann, T. Felder, C. A. Schalley, B. Kirchner