Cycloaddition Reactions of Active Cyclic Frustrated Lewis Pairs

• Applicant: Professor Dr. Gerhard Erker
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation ; Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2018 to 2021
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 411668360

• Final Report Year: 2021

Final Report Abstract

No abstract available

Publications

• Aggregation Behavior of a Six-Membered Cyclic Frustrated Phosphane/Borane Lewis Pair: Formation of a Supramolecular Cyclooctameric Macrocyclic Ring System, Angew. Chem. Int. Ed. 2019, 58, 882-886
  X. Jie, C. G. Daniliuc, R. Knitsch, M. R. Hansen, H. Eckert, S. Ehlert, S. Grimme, G. Kehr, G. Erker
  (See online at https://doi.org/10.1002/anie.201811873)
• A rare olefin 1,1-carboboration reaction opens a synthetic pathway to an unusually structured frustrated Lewis pair, Chem. Commun. 2020, 56, 8806-8809
  C. Chen, C. G Daniliuc, C. Mück-Lichtenfeld, G. Kehr, G. Erker
  (See online at https://doi.org/10.1039/D0CC01255F)
• Cycloaddition Reactions of an Active Cyclic Phosphane/Borane Pair with Alkenes, Alkynes, and Carbon Dioxide, Chem. Eur. J. 2020, 26, 1269-1273
  X. Jie, Q, Sun, C. G Daniliuc, R. Knitsch, M. R. Hansen, H. Eckert, G. Kehr, G. Erker
  (See online at https://doi.org/10.1002/chem.201905171)
• Using the FpXylBH2·SMe2 reagent for the regioselective synthesis of cyclic bis(alkenyl)boranes, Chem. Commun. 2020, 56, 12178-12181
  K. Škoch, C. G Daniliuc, G. Kehr, G. Erker
  (See online at https://doi.org/10.1039/d0cc05230b)
• Substituent dependent cyclization reactions of 1,1’-bis(alkynyl)ferrocenes with the (C6F5)BH2⋅ SMe2 hydroboration reagent, Eur. J. Inorg. Chem. 2021
  K. Škoch, C. G. Daniliuc, G. Kehr, G. Erker
  (See online at https://doi.org/10.1002/ejic.202100838)
• The Bis(µ6-benzene)lithium Cation: A Fundamental Main-Group Organometallic Species, Angew. Chem. Int. Ed. 2021, 60, 22879-22884
  X. Jie, J. Li, C. G. Daniliuc, A.-L. Wübker, M. R. Hansen, H. Eckert, C. Mück-Lichtenfeld, G. Kehr, G. Erker
  (See online at https://doi.org/10.1002/anie.202108376)