Development of Heteropolyvanadate Spin Clusters as Candidates for Future Redox-Based Memory Devices

• Applicant: Dr. Kirill Monakhov
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2015 to 2021
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 268755760

• Final Report Year: 2021

Final Report Abstract

No abstract available

Publications

• Addressing multiple resistive states of polyoxovanadates: Conductivity as a function of individual molecular redox states. J. Am. Chem. Soc. 2018, 140, 16635–16640
  O. Linnenberg, M. Moors, A. Notario-Estévez, X. López, C. de Graaf, S. Peter, C. Bäumer, R. Waser, K. Y. Monakhov
  (See online at https://doi.org/10.1021/jacs.8b08780)
• Configurational isomerism in polyoxovanadates. Angew. Chem. Int. Ed. 2018, 57, 2972–2975
  L. K. Mahnke, A. Kondinski, U. Warzok, C. Näther, J. van Leusen, C. A. Schalley, K. Y. Monakhov, P. Kögerler, W. Bensch
  (See online at https://doi.org/10.1002/anie.201712417)
• Decoding the role of encapsulated ions in electronic and magnetic properties of mixedvalent polyoxovanadate capsules {X@V22O54} (X = ClO4–, SCN–, VO2F2–): A combined theoretical approach. Phys. Chem. Chem. Phys. 2018, 20, 17847–17858
  A. Notario-Estévez, P. Kozłowski, O. Linnenberg, C. de Graaf, X. López, K. Y. Monakhov
  (See online at https://doi.org/10.1039/c8cp02669f)
• How does the redox state of polyoxovanadates influence the collective behavior in solution? A case study with [I@V18O42]q– (q = 3, 5, 7, 11 and 13). Inorg. Chem. 2019, 58, 3881–3894
  A. Solé-Daura, A. Notario-Estévez, J. J. Carbó, J. M. Poblet, C. de Graaf, K. Y. Monakhov, X. López
  (See online at https://doi.org/10.1021/acs.inorgchem.8b03508)
• Interplaying the amphipathic polyoxometalate interactions in solution and at solid–liquid interfaces: A toolbox for the technical application. Nanoscale 2019, 11, 4267–4277
  M. Glöß, R. Pütt, M. Moors, E. Kentzinger, W. Pyckhout-Hintzen, K. Y. Monakhov
  (See online at https://doi.org/10.1039/c8nr08008a)
• Self-assembled monolayers of polyoxovanadates with phthalocyaninato lanthanide moieties on gold surfaces. Chem. Commun. 2019, 55, 13554–13557
  R. Pütt, X. Qiu, P. Kozłowski, H. Gildenast, O. Linnenberg, S. Zahn, R. C. Chiechi, K. Y. Monakhov
  (See online at https://doi.org/10.1039/c9cc06852j)
• Hexavanadate–organogold(I) hybrid compounds: Synthesis by the azide–alkyne cycloaddition and density functional theory study of an intriguing electron density distribution. Inorg. Chem. 2020, 59, 16122–16126
  S. K. Petrovskii, V. V. Khistiaeva, A. A. Sizova, V. V. Sizov, A. V. Paderina, I. O. Koshevoy, K. Y. Monakhov, E. V. Grachova
  (See online at https://doi.org/10.1021/acs.inorgchem.0c02621)
• Insertion of VIV ions into the polyoxotungstate archetype {As4W40}. Inorg. Chem. 2021, 60, 8437–8441
  M. Stuckart, N. V. Izarova, M. Glöß, J. Klose, C. Schmitz-Antoniak, P. Kögerler, B. Kersting, K. Y. Monakhov
  (See online at https://doi.org/10.1021/acs.inorgchem.1c00897)
• TiOx/Pt3Ti(111) surface-directed formation of electronically responsive, supramolecular assemblies of tungsten oxide clusters. Beilstein J. Nanotechnol. 2021, 12, 203–212
  M. Moors, Y. An, A. Kuc, K. Y. Monakhov
  (See online at https://doi.org/10.3762/bjnano.12.16)
• {P2V3W15}-polyoxometalates functionalized with phthalocyaninato Y and Yb moieties. Inorg. Chem. 2021, 60, 80–86
  R. Pütt, P. Kozłowski, I. Werner, J. Griebel, S. Schmitz, J. Warneke, K. Y. Monakhov
  (See online at https://doi.org/10.1021/acs.inorgchem.0c02257)