Introduction of Nitrogen into Fluorides

• Applicant: Professor Dr. Florian Kraus
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation ; Solid State and Surface Chemistry, Material Synthesis
• Term: from 2014 to 2018
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 248350720

• Final Report Year: 2018

Final Report Abstract

No abstract available

Publications

• [Th10(μ-F16)(μ3-O4)(μ4-O4)(NH3)32](NO3)8 ∙ 19.6 NH3 – the largest Thorium Complex from Solution known to date. Zeitschrift für anorganische und allgemeine Chemie, Vol. 640. 2014, Issue 8‐9, pp. 1547-1550.
  P. Woidy, F. Kraus
  
• A New Route to Metal Azides. Angew. Chem. 2014, 126, 13913-13915, Angewandte Chemie, International Edition, Vol. 53, Issue 50. 2014, pp. 13695-13697.
  T. G. Müller, F. Karau, W. Schnick, F. Kraus
  
• Comment on “Fluorine in Shark Teeth: Its Direct Atomic-Resolution Imaging and Strenghthening Function”. Angew. Chem. 2014, 126, 5606-5607, Angew. Chem. Int. Ed. Vol. 53. 2014, Issue 22, pp. 5502-5503.
  A. J. Karttunen, F. Kraus
  
• Na2PtF6, its Crystal Structure, Characterization, and Ammonolysis to [Na(NH3)3]2[PtF6]. Zeitschrift für anorganische und allgemeine Chemie, Vol. 641, Issue 2 (Special Issue: Dedicated to Professor Arndt Simon on the Occasion of His 75th Birthday and to Professor Hans‐Jörg Deiseroth on the Occasion of His 70th Birthday), pp. 298-303.
  S. S. Rudel, T. G. Müller, F. Kraus
  
• On Copper(I)-Fluorides, the Cuprophilic Interaction, the Preparation of Copper Nitride at Room Temperature and its Formation Mechanism at Elevated Temperatures. Chemistry — A European Journal, Vol. 21. 2015, Issue 8, pp. 3290-3303.
  P. Woidy, A. J. Karttunen, M. Widenmeyer, R. Niewa, F. Kraus
  
• Crystal structure of [Ag(NH3)3]2[Ag(NH3)2]2[SnF6]F2, a compound showing argentophilic interactions. Acta Crystallographica, E Crystallogr Commun., Vol. 72. 2016), pp. 1860-1863.
  F. Kraus, M. Fichtl, S. Baer
  
• Trace determination and pressure estimation of fluorine F2 caused by irradiation damage in minerals and synthetic fluorides. Chemistry — A European Journal, Vol. 22. 2016, Issue 51, pp. 18388-18393.
  V. R. Celinski, M. Ditter, F. Kraus, F. Fujara, J. Schmedt auf der Günne
  
• A 1D Coordination Polymer of UF5 with HCN as a Ligand. Chemistry — A European Journal, Vol. 23. 2017, Issue 2, pp. 291-295.
  B. Scheibe, S. S. Rudel, M. R. Buchner, A. J. Karttunen, F. Kraus
  
• The decomposition products of sulfur hexafluoride (SF6) with metals dissolved in liquid ammonia. Inorganics, Vol. 5. 2017, Issue 4, 68.
  H. L. Deubner, F. Kraus
  
• Recent Advances in the Chemistry of Uranium Halides in Anhydrous Ammonia. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 233. 2018, Issue 12, pp. 817-844.
  S. S. Rudel, S. A. Baer, P. Woidy, T. G. Müller, H.-L. Deubner, B. Scheibe, F. Kraus